{"id":20378,"date":"2025-10-26T09:00:58","date_gmt":"2025-10-26T00:00:58","guid":{"rendered":"https:\/\/blog.agentsoft.co.kr\/index.php\/2025\/10\/26\/20378\/"},"modified":"2025-10-26T09:00:58","modified_gmt":"2025-10-26T00:00:58","slug":"pcc%eb%a5%bc-%ec%9d%b4%ec%9a%a9%ed%95%9c-%ec%82%b0%ed%99%94-%ed%99%98%ec%9b%90-%eb%b0%98%ec%9d%91","status":"publish","type":"post","link":"https:\/\/blog.agentsoft.co.kr\/index.php\/2025\/10\/26\/20378\/","title":{"rendered":"PCC\ub97c \uc774\uc6a9\ud55c \uc0b0\ud654 \ud658\uc6d0 \ubc18\uc751"},"content":{"rendered":"

<\/p>\n

\ubaa9\ucc28<\/strong><\/p>\n

1. Title
\n2. Purpose
\n3. Theory
\n4. Apparatus and Reagents
\n5. Procedure
\n6. Cautions
\n7. Data & Results
\n8. Discussion
\n9. Conclusion
\n10. References<\/p>\n

\ubcf8\ubb38\ub0b4\uc6a9<\/strong><\/p>\n

1. Title
\nCitronellal from Citronellol (Oxidation With PCC) & Reduction of 4-t-Butylcyclohexanone with NaBH4<\/p>\n

2. Purpose
\n– \uc0b0\ud654\uc81c\uc778 PCC(pyridinium chlorochromate)\ub97c \uc774\uc6a9\ud558\uc5ec citronellol\ub85c\ubd80\ud130 aldehyde\uc778 citronellal\uc744 \ud569\uc131\ud558\uace0 alcohol\uc758 \uc0b0\ud654\ubc18\uc751\uc744 \uc774\ud574\ud55c\ub2e4.
\n– \ud658\uc6d0\uc81c\uc778 sodium borohydride\ub97c \uc774\uc6a9\ud558\uc5ec 4-t-butylcyclohexanone\uc744 reduction\ud558\uc5ec 4-tbutylcyclohexanol\uc744 \ud569\uc131\ud558\uc5ec ketone\uc758 reduction \ubc18\uc751\uc744 \uc774\ud574\ud55c\ub2e4.<\/p>\n

3. Theory
\n356 390 467
\n1) Oxidation of Alcohol (1,2,3\ucc28)
\n\uc720\uae30\ud654\ud559\uc5d0\uc11c \uc0b0\ud654\ub294 O2, Br2\uc640 \uac19\uc740 \uc0b0\ud654\uc81c\ub97c \ucca8\uac00\ud574 \uc77c\uc5b4\ub098\ub294 \ubc18\uc751, \ud658\uc6d0\uc740 H2, NaBH4\uc640 \uac19\uc740 \ud658\uc6d0\uc81c\ub97c \ucca8\uac00\ud558\uc5ec \uc77c\uc5b4\ub098\ub294 \ubc18\uc751\uc774\ub77c\uace0 \uc77c\uceeb\ub294\ub2e4. \uc54c\ucf54\uc62c\uc774 \uc0b0\ud654\ub418\uba74 ketone, aldehyde, carboxyl acid\uac00 \ub41c\ub2e4. Alcohol\uc740 C\uc5d0 \uacb0\ud569\ud55c alkyl group\uc758 \uac1c\uc218\uc5d0 \ub530\ub77c 1\ucc28, 2\ucc28, 3\ucc28 alcohol\ub85c \uad6c\ubd84\ub418\uba70 \uac01 alcohol\uc740 \ub2e4\ub978 \uc591\uc0c1\uc758 oxidation mechanism\uc744 \uac00\uc9c4\ub2e4.<\/p>\n

1\ucc28 alcohol
\n1\ucc28 alcohol\uc744 \uc0b0\ud654\ud558\uae30 \uc704\ud574\uc11c\ub294 \uc544\uc8fc \uac15\ub825\ud55c \uc0b0\ud654\uc81c\ub97c \uc0ac\uc6a9\ud574\uc57c \ud55c\ub2e4. \uc774\ub54c \uc8fc\ub85c \ud06c\ub85c\ubbb4\uc0b0 (H2CrO4)\ub97c \uc0b0\ud654\uc81c\ub85c \uc0ac\uc6a9\ud55c\ub2e4. 1\ucc28 alcohol\uc740 Figure 1\uacfc \uac19\uc740 mechanism\uc744 \ud1b5\ud574 \uc9c4\ud589\ub41c\ub2e4. \uba3c\uc800, 1\ucc28 alcohol\uc758 O\uc640 \ud06c\ub85c\ubbb4\uc0b0\uc774 \ubc18\uc751\ud574 \ubb3c\uc744 \ub0b4\ub193\uace0 Chromic ester\ub97c \uc0dd\uc131\ud55c\ub2e4. \uc0dd\uc131\ub41c Chromic ester\ub294 \ub2e4\uc2dc \ubb3c\uacfc \ubc18\uc751\ud574 aldehyde\uc640 HCrO3-\uc744 \uc0dd\uc131\ud55c\ub2e4. \uc774\ub54c \uc0ac\uc6a9\ud55c \uc0b0\ud654\uc81c\uc778 \ud06c\ub85c\ubbb4\uc0b0\uc740 \ub9e4\uc6b0 Figure 1 1\ucc28 alcohol\uc758 oxidation mechanism \uac15\ud55c \uc0b0\ud654\uc81c\uc774\ubbc0\ub85c, \ub2e4\uc2dc aldehyde\ub97c \uc0b0\ud654\uc2dc\ucf1c carboxylic acid\ub97c \ub9cc\ub4e0\ub2e4<\/p>\n

\ucd9c\ucc98 : \ud574\ud53c\ucea0\ud37c\uc2a4<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\ubaa9\ucc28 1. Title 2. Purpose 3. Theory 4. Apparatus and Reagents 5. Procedure 6. Cautions 7. Data & Results 8. Discussion 9. Conclusion 10. References \ubcf8\ubb38\ub0b4\uc6a9 1. Title Citronellal from Citronellol (Oxidation With PCC) & Reduction of 4-t-Butylcyclohexanone with NaBH4 2. Purpose – \uc0b0\ud654\uc81c\uc778 PCC(pyridinium chlorochromate)\ub97c \uc774\uc6a9\ud558\uc5ec citronellol\ub85c\ubd80\ud130 aldehyde\uc778 citronellal\uc744 \ud569\uc131\ud558\uace0 alcohol\uc758 \uc0b0\ud654\ubc18\uc751\uc744 \uc774\ud574\ud55c\ub2e4. – […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[4195,15740,11936],"class_list":["post-20378","post","type-post","status-publish","format-standard","hentry","category-uncategorized","tag-a-","tag-15740","tag-11936"],"_links":{"self":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts\/20378","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/comments?post=20378"}],"version-history":[{"count":0,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts\/20378\/revisions"}],"wp:attachment":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/media?parent=20378"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/categories?post=20378"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/tags?post=20378"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}