{"id":6956,"date":"2025-06-14T09:00:23","date_gmt":"2025-06-14T00:00:23","guid":{"rendered":"https:\/\/blog.agentsoft.co.kr\/index.php\/2025\/06\/14\/6956\/"},"modified":"2025-06-14T09:00:23","modified_gmt":"2025-06-14T00:00:23","slug":"a-%ec%9c%a0%ea%b8%b0%ed%99%94%ed%95%99%ec%8b%a4%ed%97%981-oxidation-and-reduction-%eb%a0%88%ed%8f%ac%ed%8a%b8","status":"publish","type":"post","link":"https:\/\/blog.agentsoft.co.kr\/index.php\/2025\/06\/14\/6956\/","title":{"rendered":"A+ \uc720\uae30\ud654\ud559\uc2e4\ud5d81 < Oxidation and Reduction > \ub808\ud3ec\ud2b8"},"content":{"rendered":"

<\/p>\n

\ubaa9\ucc28<\/strong><\/p>\n

1. Title<\/p>\n

2. Purpose<\/p>\n

3. Theory
\n 3.1 Oxidation and Reduction
\n 3.2 Oxidation of alcohol
\n 3.3 Cr(\u2165)\uc758 \uc54c\ucf54\uc62c \uc0b0\ud654 mechanism
\n 3.4 PCC and PDC
\n 3.5 Other oxidation
\n 3.6 Terpene
\n 3.7 Reduction of carbonyl compound
\n 3.8 Other reducing regent
\n 3.9 Molecular sieves (MS)<\/p>\n

4. Reagents & Apparatus
\n 4.1 Reagents
\n 4.2 Physical properties of chemical reagents
\n 4.3 Apparatus
\n 4.4 Apparatus set-up<\/p>\n

5. Procedure<\/p>\n

6. \uc2e4\ud5d8 \uc2dc \uc8fc\uc758\ud574\uc57c \ud560 \uc0ac\ud56d<\/p>\n

7. Data & Results
\n 7.1 \ubc18\uc751 \ubcc0\ud654 \uad00\ucc30
\n 7.2 Yield
\n 7.3 TLC
\n 7.4 1H-NMR spectrum<\/p>\n

8. Discussion
\n 8.1 \ubc18\uc751\uc5d0 \ub300\ud55c \ubd84\uc11d
\n 8.2 \uc2e4\ud5d8 \uacfc\uc815\uc5d0 \ub300\ud55c \ubd84\uc11d
\n 8.3 TLC \uacb0\uacfc \ubd84\uc11d
\n 8.4 1H-NMR Spectrum \ubd84\uc11d
\n 8.5 Yield \ubd84\uc11d<\/p>\n

9. Conclusion<\/p>\n

10. References<\/p>\n

\ubcf8\ubb38\ub0b4\uc6a9<\/strong><\/p>\n

1. Title : Citronellal from Citronellol (Oxidation with PCC)& Reduction of 4-t-butylcyclohexanone with NaBH4<\/p>\n

2. Purpose
\n\uc0b0\ud654\uc81c\uc778 pyridinium chlorochromate\ub97c \uc774\uc6a9\ud574 citronellol\ub85c\ubd80\ud130 aldehyde\uc778 citronellal\uc744 \ud569\uc131\ud55c\ub2e4. \uc774\ub97c \ud1b5\ud574 alcohol\uc758 \uc0b0\ud654 \ubc18\uc751\uc744 \uc774\ud574\ud55c\ub2e4.
\n\ud658\uc6d0\uc81c\uc778 sodium borohydride\ub97c \uc774\uc6a9\ud574 4-t-butylcyclohexanone\uc744 \ud658\uc6d0\uc2dc\ucf1c 4-t-butylcylcohexanol\uc744 \ud569\uc131\ud55c\ub2e4. \uc774\ub97c \ud1b5\ud574 ketone\uc758 \ud658\uc6d0 \ubc18\uc751\uc744 \uc774\ud574\ud55c\ub2e4.<\/p>\n

<\uc911 \ub7b5><\/p>\n

9. Conclusion
\n\uc774\ubc88 \uc2e4\ud5d8\uc5d0\uc11c\ub294 PCC\ub97c \uc774\uc6a9\ud558\uc5ec citronellol\uc744 citronellal\ub85c \uc0b0\ud654\uc2dc\ucf30\ub2e4. \ubc18\uc751 \uacfc\uc815 \uc911 \uc218\ubd84\uc774 \uc720\uc785\ub418\ub294 \uac83\uc744 \ub9c9\uace0\uc790 4A MS\ub97c \ud568\uaed8 \ucca8\uac00\ud558\uc600\ub2e4. \uc774\ud6c4 product\ub97c \uc5bb\uc5b4 TLC\uc640 NMR\ub85c \ubd84\uc11d\ud55c \uacb0\uacfc, product \ubfd0\ub9cc \uc544\ub2c8\ub77c byproduct \ub610\ud55c \ud569\uc131\ub418\uc5c8\uc74c\uc744 \ud655\uc778\ud560 \uc218 \uc788\uc5c8\ub2e4. byproduct\ub294 proton\uacfc \uc218\ubd84\uc758 \uc720\uc785\uc5d0 \uc758\ud55c \uac83\uc73c\ub85c \ubd84\uc11d\ub41c\ub2e4. \uc774\ubc88 \uc2e4\ud5d8\uc5d0\uc11c\ub294 \ub610\ud55c NaBH4\ub97c \uc774\uc6a9\ud558\uc5ec 4-t-butylcylcohexanol\ub85c \ud658\uc6d0\uc2dc\ucf30\ub2e4. \ubc18\uc751 \ud6c4 NaBH4\ub97c quenching \ud558\uace0\uc790 HCl\uc744 \ub123\uc5c8\ub2e4. \uadf8 \uacb0\uacfc quenching\uc774 \uc77c\uc5b4\ub098\uba70 \uae30\uccb4\uac00 \ubc1c\uc0dd\ud558\ub294 \uac83\uc744 \ud655\uc778\ud558\uc600\uace0, \ubb34\uc5c7\uc778\uc9c0 \ubd84\uc11d\ud558\uc600\ub2e4. product\uc744 TLC\uc640 NMR\ub85c \ubd84\uc11d\ud55c \uacb0\uacfc, 4-t-butylcylcohexanol\uc774 \ud569\uc131\ub418\uc5c8\uc73c\uba70, \uc774\uac83\uc774 Cis \ud615\uacfc Trans \ud615\uc73c\ub85c \uc774\uc131\uc9c8\uccb4\uac00 \uc0dd\uacbc\uc74c\uc744 \uc54c \uc218 \uc788\uc5c8\ub2e4. NMR\uc758 \uba74\uc801 \ube44\ub97c \ud1b5\ud558\uc5ec Trans: Cis=4:1\uc784\uc744 \ubc1d\ud600\ub0c8\ub2e4.<\/p>\n

\ucd9c\ucc98 : \ud574\ud53c\ucea0\ud37c\uc2a4<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\ubaa9\ucc28 1. Title 2. Purpose 3. Theory 3.1 Oxidation and Reduction 3.2 Oxidation of alcohol 3.3 Cr(\u2165)\uc758 \uc54c\ucf54\uc62c \uc0b0\ud654 mechanism 3.4 PCC and PDC 3.5 Other oxidation 3.6 Terpene 3.7 Reduction of carbonyl compound 3.8 Other reducing regent 3.9 Molecular sieves (MS) 4. Reagents & Apparatus 4.1 Reagents 4.2 Physical properties of chemical reagents 4.3 […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[11950,11949,4967,11951,11952,5955,11935,11936],"class_list":["post-6956","post","type-post","status-publish","format-standard","hentry","category-uncategorized","tag-citronellal","tag-citronellol","tag-ipcc-6-","tag-oxidation","tag-reduction","tag-5955","tag-11935","tag-11936"],"_links":{"self":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts\/6956","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/comments?post=6956"}],"version-history":[{"count":0,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/posts\/6956\/revisions"}],"wp:attachment":[{"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/media?parent=6956"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/categories?post=6956"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/blog.agentsoft.co.kr\/index.php\/wp-json\/wp\/v2\/tags?post=6956"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}